期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 703, 期 -, 页码 163-173出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.01.272
关键词
Activated carbon; Manganous-manganic oxide; Hierarchical porous structure; Supercapacitor; Electrochemical performances
资金
- National Natural Science Foundation of China [51262029]
- Program for Excellent Young Talents, Yunnan University [XT412003]
The natural coconut shell activated carbon (AC) was firstly treated with KOH in advance, and the Mn3O4/AC composites in various AC rations were prepared by the hydrothermal process and subsequent heat treatment. The resulting Mn3O4/AC composites were characterized by means of different techniques including X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and so on. Morphological studies reveal the hierarchical porous structure of Mn3O4/AC composites. Mn3O4/AC nanocomposite with the activated carbon quality percentage of 10% exhibits the highest specific capacitance of 491.2 F g(-1) at the current density of 2 A g(-1) in 6 M KOH aqueous electrolyte measured from the charge-discharge process. The value is nearly 6 times higher than that of the pure Mn3O4 nanoparticles as an electrode for supercapacitor. The good performance of the as-prepared Mn3O4/AC composites as electrode materials may be attributed to the synergistic effects of the activated carbon and the Mn3O4. (C) 2017 Elsevier B.V. All rights reserved.
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