期刊
DALTON TRANSACTIONS
卷 49, 期 5, 页码 1384-1387出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt04684d
关键词
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资金
- KAKENHI from the Japan Society for the Promotion of Science [17H06444, 19H00903, 17K19185, 17H05391, 19H04602, 17K08206]
- JST ACT-C, Japan [JPMJCR12YH]
- Mitsubishi Foundation
- Tokuyama Science Foundation
- Grants-in-Aid for Scientific Research [19H04602, 17K08206] Funding Source: KAKEN
A pentanuclear cobalt complex that consists of five cobalt ions and six bpp(-) ligands (Co5, Hbpp = 3,5-bis(2-pyridyl)pyrazole) was synthesized and crystallographically characterized. Electrochemical measurements indicate that Co5 has multielectron transfer ability. We also found that Co5 reduces CO2 to CO under photoirradiation in the presence of a photosensitizer.
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