期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 31, 页码 4328-4331出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc01140a
关键词
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资金
- EPSRC [EP/M024210]
- Leverhulme Trust [RPG2015-447]
- SCG Chemicals
- EPSRC [EP/M024210/2, EP/M024210/1] Funding Source: UKRI
Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the sigma-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BAr4F]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.
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