期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 8, 期 14, 页码 6822-6827出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ta02016h
关键词
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资金
- National Key Research and Development Program of China [2019YFA0205700]
- National Natural Science Foundation of China [51602219, 51671145, 51761165012]
- National Science Fund for Distinguished Young Scholars [51825102]
- Tianjin Youth Thousand Talents Program
- Tianjin Municipal Science and Technology Commission [17JCYBJC42000]
Dendrite-associated cell degradation is a key challenge to the practical application of sodium metal anodes. Here, we present that incorporation of a tiny amount of mercury into sodium generates a unique quasi-liquid interface that affords long-term cycling stability. This amalgam layer allows fast electron transfer and sodium migration at the electrolyte-electrode interphase, which significantly promote the cycling performance over 5000 h with a practically desired capacity of 2 mA h cm(-2) and a current density of 8 mA cm(-2). In situ optical microscopy analyses confirm that dendrite nucleation and growth can be remarkably suppressed with the amalgam-protected anodes. Prototype full cells also demonstrate a much improved rate and long-term cycling stability. These promising results provide new perspectives on the regulation of sodium electrodeposition by introducing low-melting metals and hence the elimination of the dendritic morphology for the practical development of sodium metal batteries.
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