期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 18, 页码 2767-2770出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc10030j
关键词
-
资金
- Ogasawara Foundation
- [19J11097]
- [JP19K05582]
We synthesized glyco-arylopeptides, whose folding structure significantly changes depending on the kind of saccharide in their side chain. The saccharide moiety interacts with the main chain via hydrogen bonding, and the non-natural polypeptides form two well-defined architectures-(P)-3(1)- and (M)-4(1)-helices-depending on the length of the saccharide chains and even the configuration of a single stereo-genic center in the epimers.
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