期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 22, 页码 3305-3308出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00477d
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资金
- Centre National de la Recherche Scientifique (CNRS)
A cationic NHC 1(+) bearing an N-bound 2,3-bis(diisopropylamino)cyclopropenium group is reported. From an easily available dicationic imidazolium precursor, the coordination abilities and stereo-electronic properties of 1(+) are evaluated by the formation of Pd(ii), Rh(i) and Au(i) complexes. The cationic gold(i) complex is implemented in representative intramolecular Au(i)-catalyzed cyclizations.
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