4.7 Article

N-Cyclopropenio-imidazol-2-ylidene: An N-heterocyclic carbene bearing an N-cationic substituent

期刊

CHEMICAL COMMUNICATIONS
卷 56, 期 22, 页码 3305-3308

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00477d

关键词

-

资金

  1. Centre National de la Recherche Scientifique (CNRS)

向作者/读者索取更多资源

A cationic NHC 1(+) bearing an N-bound 2,3-bis(diisopropylamino)cyclopropenium group is reported. From an easily available dicationic imidazolium precursor, the coordination abilities and stereo-electronic properties of 1(+) are evaluated by the formation of Pd(ii), Rh(i) and Au(i) complexes. The cationic gold(i) complex is implemented in representative intramolecular Au(i)-catalyzed cyclizations.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据