期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 33, 页码 4603-4606出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00636j
关键词
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资金
- National Key Research and Development Program of China [2017YFA0302904, 2016YFA0300303, 2017YFA0303000, 2017YFA0504703]
- National Basic Research Program of China [2015CB921304]
- National Natural Science Foundation of China [11774391, 11774403, 11804381]
- Strategic Priority Research Program (B) of the Chinese Academy of Sciences [XDB25000000, XDB07020000]
- Scientific Instrument Developing Project of the Chinese Academy of Sciences [ZDKYYQ20170002]
Using 2% percent of iron dopants as reaction active sites yields a series of single crystals of 1,10-phenanthroline intercalated NiPS3, via a solution reaction with aniline chloride, not possible by a direct reaction. Experimental magnetic susceptibility measurements demonstrate that 1,10-phenanthroline intercalation suppresses the anti-ferromagnetism ordering at around 150 K in Fe0.02Ni0.98PS3, and gives rise to a ferrimagnetic phase transition at a temperature around 75 K. An intercalation mechanism is proposed for the reaction, and this dopant seeding method provides a new approach for intercalation into layered materials.
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