期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 32, 页码 4381-4395出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00672f
关键词
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资金
- ImPACT Program of the Council for Science, Technology, and Innovation (Cabinet Office, Government of Japan)
- MEXT of Japan [JP26288062, JP18H02035]
- JSPS of Japan [JP19H05721]
- JST-Mirai Program Japan [JPMJMI18E3]
- Research Grant Program from Ogasawara Foundation for the Promotion of Science Engineering
- Iketani Science and Technology Foundation
- Asahi Glass Foundation
- Murata Science Foundation
The introduction of non-covalent bonds is effective for achieving self-healing properties because they can be controlled reversibly. One approach to introduce these bonds into supramolecular materials is use of host-guest interactions. This feature article summarizes the development of supramolecular materials constructed by non-covalent cross-linking through several approaches, such as host-guest interactions between host polymers and guest polymers, 1 : 2-type host-guest interactions, and hostguest interactions from the polymerization of host-guest inclusion complexes. Host-guest interactions show self-healing functions while also enabling stimuli-responsiveness (redox, pH, and temperature). The self-healing function of supramolecular materials is achieved by stress dispersion arising from host-guest interactions when stress is applied. Reversible bonds based on host-guest interactions have tremendous potential to expand the variety of functional materials.
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