期刊
ANALYST
卷 145, 期 6, 页码 2106-2110出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9an01970g
关键词
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资金
- European Union [FKZ: 2011 FE 9048, 2011 VF 0016]
- state of Thuringia [FKZ: 2011 FE 9048, 2011 VF 0016]
- COST Action Nanospectroscopy [MP1302]
- Deutsche Forschungsgemeinschaft [CRC 1278]
- Thuringer Aufbaubank [2011SE9048]
- Alexander von Humboldt fellowship
Surface plasmons can provide a novel route to induce and simultaneously monitor selective bond formation and breakage. Here pH-induced protonation, followed by plasmon-induced deprotonation of 2-mercaptopyridine was investigated using surface- and tip-enhanced Raman scattering (SERS and TERS). A large difference in the deprotonation rate between SERS and TERS will be demonstrated and discussed with respect to hot-spot distribution.
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