期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 8, 期 4, 页码 1380-1390出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9tc05704h
关键词
-
资金
- National Natural Science Foundation of China [21644003, 21704006]
- Natural Science Foundation of Jilin Province [2018052008JH, 20190201280JC, 20180101193JC, 20190201301JC]
In order to improve the first-order hyperpolarizability (beta) of the chromophore and transform it into a high macroscopic electro-optic activity, a series of novel second-order nonlinear optical chromophores with different push-pull electron groups introduced on the thiophene pi-conjugate bridge for tuning the shape and dipole moment (mu) of chromophores were designed and synthesized. These chromophores are based on the same thiophene pi-conjugated bridge, where the donor (N,N-diethylaniline) and acceptor (2-(3-cyano-4,5,5-trimethylfuran-2(5H)-ylidene)malononitrile or malononitrile) are linked to positions 2 and 3 of thiophene, respectively, affording a boomerang-like shape instead of a rod-like shape. Besides, an electron-poor group, Br (bromine atom), or an electron-rich group, DEA (N,N-diethylaniline), as an auxiliary acceptor or donor are linked to position 5 of thiophene. In addition, all chromophores showed good thermal stability as per the results from the DSC and TGA analysis. Through UV-vis analysis and DFT calculation, it has been concluded that chromophores with additional electron-rich groups as auxiliary donors display better intermolecular charge-transfer (ICT) absorption and lower HOMO-LUMO energy gaps (Delta E). Furthermore, the boomerang-like chromophore with the same push-pull structure shows a smaller dipole moment (mu) and beta value than the traditional FTC. The poling results of guest-host EO polymers FTC/APC, FTC-H/APC, FTC-Br/APC and FTC-DEA/APC with the same number density afford r(33) values of 17 pm V-1, 11 pm V-1, 10 pm V-1 and 25 pm V-1, respectively. Although the beta value of FTC-DEA is smaller than that of FTC, the r(33) value of FTC-DEA (25 pm V-1) is 47% greater than that of FTC (17 pm V-1) under the same number density. Hence, the above-mentioned results indicated that regulating the conjugate position of chromophores can efficiently decrease the dipole moment of the chromophores, weakening the dipole-dipole interactions and thereby enhancing the macroscopic electro-optical activity of poled polymers. These results indicate the potential application of these novel chromophores in electro-optical devices.
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