期刊
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
卷 65, 期 31, 页码 6582-6587出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jafc.7b02591
关键词
1,8-naphthalic anhydride; antidotes; delivery systems; glycyrrhizic acid; arabinogalactan; sodium salt of carboxymethyl cellulose; nuclear magnetic resonance; mechanochemistry
资金
- Russian Foundation for Basic Research [15-04-02538, 15-29-05792]
To increase the bioavailability of plant protection products, we have applied a new approach based on noncovalent association with natural water-soluble polysaccharides and oligosaccharides as delivery systems (DSs). The mechanochemical technique has been applied to prepare the solid-state nanodispersed compositions of antidote 1,8-naphthalic anhydride (NA) with arabinogalactan; sodium salt of carboxymethylcellulose, and glycyrrhizin as DSs. The effect of DSs on the solubility and the penetration of NA into the seeds of barley and wheat has been investigated by various physicochemical techniques. All DSs considerably enhance the solubility of NA and improve its penetration into the grain. The influence of polysaccharides and oligosaccharides on artificial lipid membranes was studied by the NMR relaxation method. It was concluded that the effect of polysaccharides and oligosaccharides on the penetration efficacy of plant protection products might be associated with the detected solubility enhancement and the affinity of DSs to the surface of cell membranes.
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