期刊
ACS APPLIED NANO MATERIALS
卷 3, 期 4, 页码 3252-3263出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsanm.9b02568
关键词
hierarchical zeolite; nanosphere; aluminosilicate nanobeads; alkylation; ethylbenzene
资金
- Vidyasirimedhi Institute of Science and Technology
- Thailand Toray Science Foundation
- Office of Higher Education Commission
- National Nanotechnology Center (NANOTEC), NSTDA, Ministry of Science and Technology, Thailand, through its program of Research Network NANOTEC
- Thailand Research Fund [MRG6180099]
As the catalytic performances typically depend on various factors, especially the distribution of Al species in the zeolite framework, in this contribution, hierarchical nanospherical ZSM-5 zeolites have been successfully synthesized using uniform aluminosilicate (AS) nanobeads containing silica and alumina species as a starting material to improve the Al dispersion in the framework. The synthesized zeolites were characterized by means of XRD, TEM, SEM, EDS, N-2 physisorption, Al-27 MAS NMR, and NH3-TPD. This example demonstrates that the use of AS nanobeads can effectively control the uniform Al distribution. Subsequently, the synthesized materials were tested for their catalytic activity in the alkylation of benzene with ethanol to ethylbenzene. Interestingly, the designed ZSM-5 nanospheres prepared by using AS nanobeads clearly exhibit an improvement of the catalytic performance in terms of benzene conversion and ethylbenzene selectivity compared with the conventional ZSM-5 and the ZSM-5 nanospheres prepared by using a typical synthesis method. The reason for the improved benzene conversion (60%) and ethylbenzene selectivity (62%) on Hie-SZSM-5-AS relates to the generated mesoporous structure as well as a homogeneous distribution of Al frameworks directed by AS nanobeads. The synthesis approach reported herein illustrates an efficient way to control Al species as well as Al distribution in the zeolite framework, eventually enhancing the catalytic performance in acid catalyzed reaction, such as in the case of benzene alkylation with ethanol.
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