期刊
ACS APPLIED ENERGY MATERIALS
卷 3, 期 4, 页码 4043-4050出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.0c00491
关键词
hyperbranched polymers; carbon nanotubes; supercapacitor; flexibility; template; NiCo2O4
资金
- National Natural Science Foundation of China [51873233, 51703250]
- Hubei Natural Science Foundation [2018CFA023]
- Hubei Major Projects of Technological Innovation [2017AAA131]
- Fundamental Research Funds for the Central Universities [CZP20006]
The lightweight carbon nanotube (CNT) has been attracting great attention in the field of flexible electronics, but it is still a challenge to increase both high capacitance and high energy density. Here, we report the use of an epoxy-ended hyperbranched polymer (EHP) as a reactive template in an in situ preparation of porous NiCo2O4 on a pristine CNT film. The resultant porous NiCo2O4 has a core-shell nanostructure and possesses higher surface area and electrochemical performance in comparison to NiCo2O4 prepared without CNT film. As an electrode material, the CNT (2) NiCo2O4 film showed a high specific volume capacitance of 281.7 F cm(-3). The flexible symmetric supercapacitor assembled from the CNT(g) NiCo2O4 film displayed high volume capacitance (23.3 F cm(-3)), 95.6% retention in capacitance after 5000 charging-discharging cycles and bending performance, and high energy density (3.2 mWh cm(-3)). The CNT film served as a flexible current collector, and porous NiCo2O4 supplied high electrochemical performance. The reaction mechanism using the epoxy-ended hyperbranched polymer as a reactive template in the preparation of porous NiCo2O4 has been investigated using FT-IR, XRD, and TG.
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