4.7 Article

Self-assembly of an organometallic Fe9O6 cluster from aerobic oxidation of (tmeda)Fe(CH2tBu)2

期刊

CHEMICAL COMMUNICATIONS
卷 56, 期 37, 页码 4994-4997

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00011f

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资金

  1. University of Wyoming Research Office
  2. UW Department of Chemistry
  3. UW School of Energy Resources
  4. UW Center for Photoconversion and Catalysis
  5. NSF EPSCoR
  6. National Science Foundation [CHE 0619920, NSF-RUI 1445959]
  7. National Institute of General Medical Sciences of the National Institutes of Health [2P20GM103432]
  8. University of St. Thomas
  9. College of Arts and Sciences
  10. NSF [CHE-1363274, CHE-1800554]

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Aerobic oxidation of (tmeda)Fe((CH2Bu)-Bu-t)(2) in toluene or THF solution leads to the self-assembly of a magic-sized all-ferrous oxide cluster containing the Fe9O6 subunit and bearing organometallic and diamine ligands. Mossbauer studies of the cluster are consistent with an all-ferrous assignment and magnetometry reveals complex intracluster and intercluster magnetic interactions.

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