期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 37, 页码 4994-4997出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00011f
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资金
- University of Wyoming Research Office
- UW Department of Chemistry
- UW School of Energy Resources
- UW Center for Photoconversion and Catalysis
- NSF EPSCoR
- National Science Foundation [CHE 0619920, NSF-RUI 1445959]
- National Institute of General Medical Sciences of the National Institutes of Health [2P20GM103432]
- University of St. Thomas
- College of Arts and Sciences
- NSF [CHE-1363274, CHE-1800554]
Aerobic oxidation of (tmeda)Fe((CH2Bu)-Bu-t)(2) in toluene or THF solution leads to the self-assembly of a magic-sized all-ferrous oxide cluster containing the Fe9O6 subunit and bearing organometallic and diamine ligands. Mossbauer studies of the cluster are consistent with an all-ferrous assignment and magnetometry reveals complex intracluster and intercluster magnetic interactions.
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