期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 37, 页码 5010-5013出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09869k
关键词
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资金
- National Natural Science Foundation of China [21672047]
- SKLUWRE [2018DX02]
- Science and Technology Plan of Shenzhen [JCYJ20180306172044124]
Reported herein is a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines, which features exclusive N-CH3 selectivity for the amine partners. Mechanistic studies indicate that an in situ generated N-iodoaminium species serves as the key intermediate.
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