期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 8, 期 17, 页码 8575-8585出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta14085a
关键词
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资金
- Scientific Research Start-up Foundation of Dongguan University of Technology [3005-196100040008]
- Basic and Applied Basic Research Foundation of Guangdong Province [2019A1515110558]
- China Postdoctoral Science Foundation [2019M663733, 2019M653582]
- Natural Science Foundation of Guangdong Province [2017A030310645]
- National Natural Science Foundation of China [21805034, 21805104, 21905045]
Developing cheap and highly active oxygen reduction reaction (ORR) electrocatalysts is of great importance for fuel cells and Zn-air batteries. Transition-metal nitrides are theoretically promising ORR catalysts, but their actual ORR performance is disappointing. Insufficient d electrons, low exposure of active sites and low conductivity are the three obstacles preventing transition-metal nitrides from being competitive ORR catalysts. Herein, we introduce a comprehensive solution that manages to remove all these obstacles and improve the ORR activity of transition-metal nitrides to the level of leading non-noble metal ORR catalysts. We first prepared a Cr/Z8C material by dispersing ZIF-8 derived carbon in an ethanol solution of CrCl3 followed by a nitridation process. Using the ZIF-8-derived carbon as a support, we managed to acquire very small CrN nanoparticles, overcoming their aggregation and enhancing their conductivity. By further doping with Fe or Co, we enriched the d electrons of CrN and enhanced its adsorption to oxygen. The Fe-doped Cr/Z8C material exhibited extraordinary ORR activity. Its ORR half-wave potential in alkaline media was 44 mV higher than that of the commercial Pt/C catalyst, and its ORR half-wave potential in acidic media was only 96 mV lower than that of the commercial Pt/C catalyst. This work demonstrates the great potential of transition-metal nitrides as ORR catalysts and opens up a new road to exploit cheap and highly active ORR catalysts.
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