期刊
ACS MATERIALS LETTERS
卷 2, 期 6, 页码 565-570出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmaterialslett.0c00124
关键词
-
资金
- Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences of the U.S. Department of Energy [DE-FC02-04ER15533]
Two-dimensional (2D) lead halide perovskites represent an emerging class of materials given their tunable optoelectronic properties and long-term stability in perovskite solar cells. In order to assess the halide ion mobility, we have tracked the changes in the bromide and iodide composition in physically paired 2D lead halide perovskite films of different layer numbers (n = 10-1). These low-dimensional perovskites suppressed halide ion migration as a result of their intercalated spacer ligands and their strong van der Waals interactions. The rate constants for halide exchange of low dimensionality perovskites follow the Arrhenius relationship with thermal activation energy ranging from 58 kJ/mol (n = 10) to 72 kJ/mol (n = 1). The suppression of halide ion mobility (and diffusion coefficient) with modulating perovskite layer number (n) provides further insight into the role of 2D perovskites in improving the performance of photovoltaic devices.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据