4.7 Article

Modelling a 'histidine brace' motif in mononuclear copper monooxygenases

期刊

CHEMICAL COMMUNICATIONS
卷 56, 期 38, 页码 5123-5126

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc01392g

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资金

  1. CREST, JST [JPMJCR16P1]
  2. JSPS [19K22201]
  3. Grants-in-Aid for Scientific Research [19K22201] Funding Source: KAKEN

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A mononuclear copper complex bearing a 'histidine brace' is synthesised and characterised as an active-site model of mononuclear copper monooxygenases such as lytic polysaccharide monooxygenases (LPMOs) and particulate methane monooxygenase (pMMO). The complex has similar structural and functional features to the active sites of the enzymes.

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