期刊
RSC ADVANCES
卷 10, 期 29, 页码 16882-16885出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra02994g
关键词
-
资金
- National Natural Science Foundation of China [21272271]
(S)-5-Methyl-tetrahydropyran-2-one 1 is a by-product in the production of key intermediates of steroidal hormones. Asymmetric synthesis of natural oxacyclododecindione-type macrolactones 2 and 3 has been realized for the first time from (S)-1 in seven and eight steps with 37% and 27% overall yield, respectively.
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