期刊
DALTON TRANSACTIONS
卷 49, 期 19, 页码 6328-6340出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt00036a
关键词
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资金
- Department of Chemistry, University of Calcutta
- Department of Higher Education, Science & Technology and Biotechnology, Government of West Bengal [124(Sanc.)/ST/P/ST/15G-3/2015]
- UGC, India [UGC/740/RFSMS]
- CSIR-SRF [09/028(0983)2016-EMR-I]
- Ministerio Espanol de Ciencia e Innovacion [CTQ2016-75068P, CTQ2016-75671P]
- Unidad de Excelencia Maria de Maetzu [MDM-2015-0538]
- Ministerio de Economia y Competitividad (MINECO) [CTQ2014-56312-P]
- Ministerio de Educacion, Cultura y Deporte [PGC2018-102052-B-C21]
- Junta de Andalucia [FQM-195]
- University of Granada
- Department of Education, Universities and Research of the Basque Government
- ERDF
- ESF
Construction of efficient multifunctional materials is one of the greatest challenges of our time. We herein report the magnetic and catalytic characterization of dinuclear [(CoCoII)-Co-III(HL1)(2) (EtOH)(H2O)]Cl center dot 2H(2)O (1) and trinuclear [Co-III Co-2(II)(HL2)(2) (L-2)Cl-2]center dot 3H(2)O (2) mixed valence complexes. Relevant structural features of the complexes have been mentioned to correlate with their magnetic and catalytic properties. Unique structural features, especially in terms of significant distortions around the Co-II centre(s), prompted us to test both spin-orbit coupling (SOC) and zero field splitting (ZFS) methodologies for the systems. The positive sign of D values has been established from X-band EPR spectra recorded in the 5.- 40 K temperature range and reaffirmed by CAS/NEVPT2 calculations. ZFS tensors are also extracted for the compounds along with (CoGaIII)-Ga-II and (CoZnCoIII)-Zn-II-Co-II model species. Interestingly, 1 shows slow relaxation of magnetization below 6.5 K in the presence of a 1000 Oe external dc field with two relaxation processes (U-eff = 37.0 K with tau(0) = 157 x 10(-8) s for the SR process and U-eff = 7 K with tau(0) = 1.66 x 10(-6) s for the FR process). As mixed valence cobalt complexes with various nuclearities are central to the quest for water oxidation catalysts, we were prompted to explore their features and to our surprise, water oxidation ability has been realized for both 1 and 2 with significant nuclearity control.
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