4.3 Article

Recent Advances in the Asymmetric Claisen Rearrangement Promoted by Chiral Organometallic Lewis Acids or Organic Bronsted-Lowry Acids

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CURRENT ORGANIC SYNTHESIS
卷 12, 期 6, 页码 795-805

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BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157017941206150828112854

关键词

[3,3] sigmatropic; organocatalysis; chiral Lewis acids; claisen rearrangement; asymmetric rearrangement; catalysis

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  1. CAPES
  2. CNPq
  3. FINEP-MCT
  4. DPP-UnB

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The Claisen rearrangement, an important C-C bond forming reaction, has been used enormously for many decades in the synthesis of important class of compounds. This review covers developments in this rearrangement since 2008, discusses important aspects about the asymmetric Claisen rearrangement catalyzed by chiral organometallic Lewis acids or organic Bronsted-Lowry acids.

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