期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 18, 期 22, 页码 4257-4266出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ob00778a
关键词
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资金
- National Natural Science Foundation of China [21961034, 21502154, 21362033]
- Science and Technology Program of Gansu Province [17JR5RA073, 18JR3RA091]
An efficient sulfide-catalyzed [2 + 1] annulation ofpara-quinone methides (p-QMs) with diverse bromides has been achieved. This catalytic strategy provides an efficient and straightforward protocol for accessing a variety of spiro-cyclopropanyl-cyclohexadienone compounds in good to excellent yields (64% to 96% yields) with outstanding diastereoselectivities (>20 : 1 dr), displaying good functional group tolerance as well as gram-scale capacity.
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