Hierarchical self-assembly of helical coordination polymers and formation of a lamellar structure via the cooperativity of two-step Ag(i) coordination and π-π interactions

Hierarchical self-assembly from a V-shaped ligand 2,9-di(pyridin-4-yl)-1,10-phenanthroline (DPP) to an initial interlocked dimer, further to a coordination polymer with an alternate linear and interlocked helical configuration and finally to a lamellar structure with an undulating surface was precisely achieved in sequence via the cooperativity of two-step Ag (i) coordination and pi-pi interactions for the first time.