期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 53, 页码 7233-7236出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc02472d
关键词
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资金
- National Key R&D Program of China [2018YFA0704502, 2017YFA0206800]
- Strategic Priority Research Program of CAS [XDB20000000]
- Key Research Program of Frontier Science, CAS [QYZDY-SSW-SLH025]
- NSFC [21671189, 21731006, 21901242]
- Youth Science Research Program of Fujian Jiangxia University [JXZ2018003]
- Youth Innovation Promotion Association CAS
Three unprecedented multi-cluster copper(I) halides (MCCHs) have been assembled using conformationally flexible ligands. Further explorations demonstrate that the conformational compliance of the ligands may be the key to trap and stabilize the various copper(I)-halide clusters in one system, which opens a new way for the construction of multi-Cu(I)-cluster complexes. Moreover, the MCCHs show distinctive temperature-dependent photoluminescence.
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