4.7 Article

Regio- and diastereoselective Pd-catalyzed synthesis of C2-aryl glycosides

期刊

CHEMICAL COMMUNICATIONS
卷 56, 期 52, 页码 7175-7178

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc02175j

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资金

  1. CNRS, Universite Paris-Saclay
  2. ANR (SelFSuCHi) [ANR-18-CE07-0012]
  3. Ecole Polytechnique, la Ligue Contre le Cancer through an Equipe Labellisee 2014 grant
  4. [ANR-10-LABX-33]
  5. Agence Nationale de la Recherche (ANR) [ANR-18-CE07-0012] Funding Source: Agence Nationale de la Recherche (ANR)

向作者/读者索取更多资源

An efficient regio- and diastereoselective arylation method of readily available 2,3-glycals with various aryl iodides has been established. Using the Pd(OAc)(2)/AsPh(3)precatalytic system, this protocol proved to be general to prepare a variety of substituted C2-aryl glycosides in good yields with complete diastereoselectivity.

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