4.7 Article

One-step green approach to synthesize highly fluorescent carbon quantum dots from banana juice for selective detection of copper ions

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2020.103720

关键词

Green synthesis; Quantum dots; Fluorescent; Quantum yield; Heavy metal detection

资金

  1. project entitled Rapid detection of bacterial resistance to antibiotics based on changing optical properties of nanosized labels - Department of Biotechnology, India [DBT/IC-2/Indo-Russia/2017-19/02]
  2. Ministry of Education and Science of the Russian Federation [14.616.21.0061, RFMEFI61615x0061]

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Green synthesis of carbon quantum dots (CQDs) from natural sources always remain an attraction due to their excellent optical properties. In present work, highly fluorescent N, S co-doped CQDs (NS-CQDs) were synthesized from banana (musa acuminata) juice using a simple one-step hydrothermal process, which not required any surface passivation, oxidizing agent or inorganic salt. Transmission electron microscopic images and X-ray diffraction analysis revealed spherical shaped NS-CQDs of an average size of 1.27 nm with poor crystallinity. The proposed method offers higher quantum yield (32 %) at an excitation wavelength of 330 nm as compared to other reported natural sources-derived CQD. These synthesized NS-CQDs utilized as a fluorescent probe for the detection of Cu (II) in the water sample. The fabricated fluorescent sensor displayed the detection of copper ions in the concentration range of 1 - 800 mu g/mL with the LOD of 0.3 mu g mL(-1).

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