期刊
CHEMICAL SCIENCE
卷 11, 期 25, 页码 6370-6382出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sc01340d
关键词
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资金
- University Grants Committee Areas of Excellence Scheme [AoE/P-03/08]
- Shenzhen Science and Technology Innovation Committee [JCYJ20170412140251576, JCYJ20180508162429786]
- Hong Kong Research Grants Council [HKU 17330416]
- China Postdoctoral Science Foundation [2018M633043]
- CAS-Croucher Funding Scheme for Joint Laboratories
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(VI) complex which can be conveniently prepared at the gramscale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
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