期刊
CHEMICAL SCIENCE
卷 11, 期 25, 页码 6521-6526出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sc01260b
关键词
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资金
- DFG (Gottfried-Wilhelm-Leibniz award) [SPP1807]
- CSC
- Onassis Foundation
C(sp(3))-H and C(sp(2))-H glycosylations of structurally complex amino acids and peptides were accomplished through the assistance of triazole peptide-isosteres. The palladium-catalyzed peptide-saccharide conjugation provided modular access to structurally complexC-alkyl glycoamino acids, glycopeptides andC-aryl glycosides, while enabling the assembly of fluorescent-labeled glycoamino acids. The C-H activation approach represents an expedient and efficient strategy for peptide late-stage diversification in a programmable as well as chemo-, regio-, and diastereo-selective fashion.
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