期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 8, 期 25, 页码 8502-8506出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0tc00959h
关键词
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资金
- National Natural Science Foundation of China [21322607, 21406072, 21471056, 21676093, 91534202]
- Basic Research Program of Shanghai [15JC1401300]
- Key Scientific and Technological Program of Shanghai [14521100800]
- International Science and Technology Cooperation Program of China [2015DFA51220]
- Fundamental Research Funds for the Central Universities [222201718002]
Mn-doped 2D perovskite powders are promising phosphors for warm white light-emitting diodes (LEDs). However, it remains a challenge to solve the problem of lead toxicity and improve the photoluminescence quantum yields (PLQYs). Here, we have successfully prepared Mn-doped 2D Sn-based perovskite materials ((C8H17NH2)(2)Sn1-xMnxBr4). The PLQYs of (C8H17NH2)(2)Sn1-xMnxBr4(x= 0.26) powders reach up to 42%. The as-prepared (C8H17NH2)(2)Sn(1-x)Mn(x)Br(4)exhibits a single broad photoluminescence (PL) band, differing from the dual peaks of Mn-doped lead halide perovskite quantum dots. Theoretical conclusions and experimental results show the competitive relationship between self-trapped exciton (STE) emission from the host crystal and dopant Mn d-d transition emission. With increasing Mn dopant concentration, the PL spectra exhibit red shifts and the full width at half-maximum (FWHM) becomes larger, which is constructive for warm white LEDs. The fabricated warm white LEDs based on (C8H17NH2)(2)Sn(1-x)Mn(x)Br(4)show a warm white light correlated color temperature (CCT; 3542 K) and a high color-rendering index (R-a, 88.12). Our work provides new possibilities for optoelectronic devices based on lead-free perovskite materials.
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