Reduction roasting of hematite to magnetite using carbohydrates

Thermomagnetic analysis was conducted on phase transformations performed for synthetic and natural hematite by reduction involving various carbohydrates (starch, glucose, fructose, sucrose, and ascorbic acid). Thermo magnetic measurements were carried out using a laboratory facility that allows the automatic registration of a sample's magnetization as the temperature changes (the rate of sample heating/cooling was 65 degrees/min). The results were then analyzed. The reduction reaction of synthetic hematite for all carbohydrates starts at a temperature of similar to 350 degrees C, while the reduction of natural hematite for all carbohydrates starts at a temperature of similar to 365 degrees C. The magnetite formed by the reaction has a Curie temperature of 565 degrees C. Both magnetite and hematite are present in all transformed samples. Saturation magnetization increases to similar to 50 Am-2/kg for the samples obtained from synthetic hematite and similar to 25 Am-2/kg for the sample obtained from natural hematite. The difference in the value of saturation magnetization is attributed to a lower magnetite content for the sample obtained from natural hematite. Synthetic hematite transforms more effective, suggesting the synthetic sample is characterized by a larger surface area compared to natural hematite. (c) 2017 Elsevier B.V. All rights reserved.