期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 42, 期 7, 页码 4208-4215出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.09.132
关键词
Hydrogen permeation; Membrane separation; Hollow fiber; Tungstates; CO2
资金
- National Science Fund for Distinguished Young Scholars of China [21225625]
- Natural Science Foundation of China [21536005, 21606086]
- Nature Science Foundation of Guangdong [2014A030312007]
- Funds for Creative Reasch Groups of China [51621001]
Tungstates (Ln(6)WO(12)) are considered as one of the most promising candidates for hydrogen separation membrane materials. Among varies Ln(6)WO(12) materials, the molybdenum doped neodymium tungsten oxides have attracted increasing attention due to their sufficient mixed proton-electron conductivity and high tolerance towards acid gases, such as CO2 and H2S. The hydrogen permeation properties of the U-shaped Nd5.5W0.5Mo0.5O11.25- (delta) (NWM) hollow fiber membranes have been studied systematically in this work. A high hydrogen permeation flux of 1.29 mL/min.min(2) was obtained at 975 C-omicron using 80% H2-20% He as feed gas and humidified Ar as sweep gas. Furthermore, the U-shaped NWM hollow fiber membrane present a hydrogen permeation flux with only a slight decrease during 80 h's operation feeding with the CO2-containing gas. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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