期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 42, 期 49, 页码 29274-29282出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2017.10.069
关键词
Bimetal; FeCo-N/C catalyst; Carbonization temperature; Electrospinning; Oxygen reduction reaction
资金
- National Natural Science Foundation of China [51102064]
- Shenzhen Bureau of Science, Technology and Innovation Commission [JCYJ20160525163956782]
- China Postdoctoral Science Foundation Funded Project [2016M590278]
- Open Fund from National Engineering Research Center of Near-net-shape Forming for Metallic Materials [2015008]
Polyacrylonitrile (PAN)-based nitrogen-doped carbon nanofibers (NFs) were successfully synthesized by electrospinning technique in combination with impregnation of FeCo-containing solutions and subsequent heat treatment process. Interestingly, the temperature of heat treatment played an important role in fabricating the morphology which could further affect the oxygen reduction reaction (ORR). When the carbonized temperature was 900 degrees C, the FeCo-N/C NFs catalyst exhibited a comparable catalytic activity for oxygen reduction reaction (ORR) in 0.5 M H2SO4 electrolyte as commercial 20% Pt/C catalyst. The excellent catalytic activity may be attributed to the defect structure, high N content, and high proportional of pyridinic-N, quatemary-N and metal nitrides. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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