4.7 Article Proceedings Paper

Porous anode of lithium-oxygen battery based on double-gas-path structure

期刊

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 42, 期 50, 页码 29944-29948

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2017.06.114

关键词

Lithium-oxygen battery; Porous anode; Double-gas-path; Lithium protection; Dynamic equilibrium

资金

  1. Natural Science Foundation of China [21206083, 21373002, U1462112, 21573122]
  2. Open Foundation of Beijing Key Laboratory for Chemical Power Source and Green Catalysis [2016CX02033]
  3. Liaoning BaiQianWan Talents Program [201797]

向作者/读者索取更多资源

A lithium-oxygen battery of double-gas-path structure and porous anode is presented in this work. Different from traditional structure battery, porous anode and the gas channel of anode side are used to provide argon gas for the battery. In order to protect the anode from corrosion of oxygen which penetrates from the cathode to the anode by dynamic gas-phase equilibrium. The improvement of the battery performance is attributed to the novel structure that can protect lithium metal from the corrosion of oxygen and it also reduces the growth of dendrite. The lithium-oxygen battery based on double-gas-path structure shows long cycle life (38 cycles), high discharge specific capacity (2510 mAh g(-1)) and specific energy density (7200 W h kg(-1)). More importantly, this work will also provide new ideas and methods for the research of other metal-air battery. (C) 2017 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.

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