期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 42, 期 19, 页码 13589-13597出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.12.124
关键词
Biogas; Dry reforming; Hydrogen; Membranes; Fluidized bed
资金
- Spanish Ministerio de Economia e Innovacion (MINECO) [ENE2013-44350R]
- Spanish Society of Catalysis (SECAT)
- European Social Fund
- Government of Aragon
Biogas is a renewable resource obtained mainly from the anaerobic fermentation of agro-industrial and anthropogenic residues. The production of hydrogen by dry reforming of methane represents a potential application for this renewable energy carrier. This could play a positive contribution towards meeting the challenge of providing a global supply of energetically sustainable and environmentally friendly energy. This work combines a catalytic reaction, a separation and the catalyst regeneration in a single reactor. To this end, a two zone fluidized bed reactor (TZFBR) with hydrogen selective membranes has been employed (TZFBR + MB). The operating conditions for the process of dry reforming of biogas have been optimized experimentally, both in TZFBR and TZFBR + MB. Several catalysts were prepared (Ni/Al2O3, Ni Ce/Al2O3, Ni Co/Al2O3), characterized and tested in reactions in both TZFBR and in TZFBR + MB. Finally, the influence of using oxygen or carbon dioxide as regenerating gases in the process has been studied. Experimental results show the feasibility of using CO2 for in situ catalyst regeneration, avoiding the potential problems associated with the use of O-2. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据