期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 55, 页码 7585-7588出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc02580a
关键词
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资金
- National Natural Science Foundation of China [51878326, 21762030, 21625203, 21871126]
- China Scholarship Council [201908360088]
A new external oxidant-free electrochemical dehydrogenative cross-coupling of xanthenes and ketones for the preparation of functionalized 9-alkyl-9H-xanthenes was developed. This method enables the formation of a new C(sp(3))-C(sp(3)) bond through release of H(2)as the major byproduct at room temperature, and features mild conditions, high atom economy, excellent functional-group tolerance, scalability and facile applications in pharmaceutical chemistry.
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