期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 42, 期 28, 页码 17664-17680出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.12.128
关键词
Dual Loop solar field; Thermal oil; Molten salt; Supercritical Carbon Dioxide; Parabolic trough; Linear Fresnel
This study is focused on proposing the combination of a Dual Loop solar field, with Dowtherm A and the Solar Salt as heat transfer fluids in parabolic or linear Fresnel solar collectors, coupled to supercritical Carbon Dioxide (s-CO2) Brayton power cycle. The Dual Loop justification relies on gaining the synergies provided by the different heat transfer fluids properties. The oils advantages are related with the operating experience accumulated in numerous solar power plants deployed around the World, assuring the commercial equipment availability. Also the pipes metal corrosion with oil is much lower than with molten salt. The pipes material cost saving is significant with the oil alternative. The thermal oil main constraint is imposed by the maximum operating temperature (around 400 degrees C) for avoiding chemical decomposition and degradation, stablishing the plant threshold efficiency 37% due to Carnot principle. On the other hand the Solar Salt mixture (60%NaNO3-40%ICNO3) maximum operating temperature goes up to 550 degrees C, but the freezing point is stablished around 220 degrees C requiring pipes and equipment electrical heating for avoiding salts solidification at low temperature. Regarding the balance of plant, the sCO(2) power cycle is the most promising alternative to the actual Rankine power cycle for increasing the plant energy efficiency, reducing the solar collector aperture area and minimizing the equipment dimensions and civil work. Three Brayton cycles configurations with reheating were assessed integrated with the line-focusing Dual-Loop solar field: the simple Brayton cycle (SB), the Recompression cycle (RC), the Partial Cooling with Recompression cycle (PCRC), and the Recompression with Main Compression Intercooling (RCMCI). The power cycle operating thermodynamic parameters (split flow, reheating pressure, mass flow and pressure ratio) were optimized with unconstrained multivariable algorithms: SUBPLEX, UOBYQA and NEWUOA. The main conclusion deducted is the significant efficiency improvement when adopting the s-CO2 Brayton cycle in comparison. with the Rankine legacy solution. The Dual-Loop solar field integrated with a Rankine cycle provides a gross efficiency around 41.8%, but when coupling to s-CO2 Brayton RC or RCMCI the plant efficiency goes up to 50%. It was also demonstrated the beneficial effect of increasing the total heat exchangers (recuperators) conductance (UA) for optimizing the Brayton cycles efficiency and minimizing the solar field aperture area for a fixed power output, only limited by the minimum pinch point temperature in heat exchangers. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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