期刊
CHEMICAL SCIENCE
卷 11, 期 28, 页码 7451-7455出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sc01049a
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资金
- National Natural Science Foundation of China [NSFC 21971102]
- Guangdong Innovative Program [2019BT02Y335]
- AIST
Despite the importance ofP-chiral organophosphorus compounds in asymmetric catalysis, transition metal-catalyzed methods for accessingP-chiral phosphine derivatives are still limited. Herein, a catalytic enantioselective method for the synthesis ofP-stereogenic alkenylphosphinates is developed through asymmetric hydrophosphorylation of alkynes. This process is demonstrated for a wide range of racemic phosphinates and leads to diverseP-stereogenic alkenylphosphinates directly.
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