期刊
DALTON TRANSACTIONS
卷 49, 期 28, 页码 9583-9587出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt02326d
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资金
- Spanish Ministry of Science and Innovation [CTQ2016-80814-R]
- Junta de Andalucia [PY18-3208]
- CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI)
Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions.
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