期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 277, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2020.119199
关键词
Ultrathin g-C3N4; Metal phthalocyanine assembly; High-level-energy electron transfer; Photocatalysis; CO2 reduction
资金
- NSFC project [U1805255, 21905080]
- Basic Research Fund of Heilongjiang University in Heilongjiang Province [RCCXYJ201808]
- Special Fund for Scientific and Technological Innovation Talents of Harbin Science and Technology Bureau [2017RAQXJ101]
- Fundamental Research Fundation for Universities of Heilongjiang Province [LGYC2018JC008]
Herein, ultrathin dimension-matched metal phthalocyanine/treated g-C3N4 (MPc/T-CN) heterojunctions with exceptional photocatalytic activities for converting CO2 to CO and CH4 have been controllably constructed through a facile surface hydroxyl group-induced assembly process, in which the increased amount of hydroxyl group by treating g-C3N4 nanosheets with HNO3 solution is much crucial for this successful assembly to improve the interfacial connection via the formed hydrogen bonding. Among the used MPc, CuPc is the best modifier for T-CN comprehensively dependent on the promotion for charge transfer and CO2 activation based on the theoretical and experimental results. The photocatalytic activity of optimized CuPc/T-CN heterojunction is about 10-fold improvement under UV-vis light irradiation compared with that of pristine CN, mainly attributed to the unexpected transfer of excited high- level-energy electrons (HLEEs) from T-CN to the ligand of CuPc and then to the central metal ions (Cu2+) with potential catalytic function for CO2 reduction reactions.
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