期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 60, 页码 8464-8467出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03211e
关键词
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资金
- MEXT, Japan [20H02751]
- Samco Science and Technology Foundation
- TEPCO Memorial Foundation
- Grants-in-Aid for Scientific Research [20H02751] Funding Source: KAKEN
The activation of the silicon-silicon bond in disilane Ph2Si(mu-Pz(Me2))(2)SiPh2(1), which possesses two five-coordinate silicon centers, was achieved by a reaction with Pd(0) or Ni(0) precursors of modest steric demand to afford a dinuclear Pd complex (2) or two types of mononuclear Ni complexes (3and4), respectively.
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