期刊
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
卷 12, 期 2, 页码 1014-1024出版社
ESG
DOI: 10.20964/2017.02.38
关键词
Supercapacitor; N-doped; super-activated carbon; Melamine formaldehyde resin; Polypyrrole; Nanocomposite
资金
- NSFC [51502021, U1501242, 51561006, 51261005, 51461010, 51401059, 51361005, 51371060, 51461011]
- National Science Foundation for Post-doctoral Scientists of China [2015M570805]
- Fundamental Research Funds for the Central Universities [310831161011]
- Guangxi Natural Science Foundation [2016GXNSFFA380012, 2015GXNSFAA139282]
- Opening Fund of Guangxi Key Laboratory of Information Materials [151001-K]
- Innovation Project of Guangxi Graduate Education [2016YJCX23]
In this study, N-doped super-activated carbon material was synthesized using melamine formaldehyde (MF) resin as carbon source and sequent KOH-activation method. Polypyrrole nanofibers (PPy) were further polymerized on the MF resin derived carbon (MFC). The PPy/MFC composite possesses high surface area, which is suitable for high performance supercapacitor electrode materials. Electrochemical measurements indicate the hybrid PPy/MFC electrode yielded the highest specific capacitance of 336.8 F g(-1) at a current density of 1 A g(-1) (in 6 M KOH). The PPy/MFC electrode also keeps a high capacitance retention ratio of 94.3% after 3000 cycles. Given the potential massive production and excellent electrochemical performance, The PPy/MFC nanocomposites are promising electrode materials for supercapacitor applications.
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