期刊
INFOMAT
卷 2, 期 5, 页码 942-949出版社
WILEY
DOI: 10.1002/inf2.12058
关键词
charge-transfer resistance; fast-charging; impedance; Li plating; polarization
资金
- Army Research Laboratory
Fast-charging is highly demanded for applications requiring short charging time. However, fast-charging triggers serious problems, leading to decline in charge acceptance and energy efficiency, accelerated capacity degradation, and safety risk. In this work, a three-electrode coin cell with a Li metal reference electrode is designed to individually record the potential of two electrodes, and measure the impedance of each electrode by using a power-optimized graphite-LiNi(0.80)Co(0.15)Al(0.05)O(2)electrode couple. It is shown that regardless of the state-of-charge the Li-ion cell's impedance is contributed predominantly by the cathode, and that the cathode's impedance is dominated by the charge-transfer resistance. In consistence with the impedance results, polarization of the Li-ion cell is dominated by the cathode. It is surprised to find that no Li plating occurs on the graphite anode even if the charging rate is increased to 10 C (1 C = 1.30 mA cm(-2)). The results of this work indicate that low overall impedance with a high cathode-to-anode impedance ratio is the key to enabling safe fast-charging, and that fast-charging Li-ion batteries without Li plating on the graphite anode is possible if the cathode and graphite anode are optimistically engineered.
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