期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 61, 页码 8639-8642出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03159c
关键词
-
资金
- NSFC [21971155, 21871167]
- 1331 Project of Shanxi Province
New paracelsian-like beryllophosphates M(4)LiBe(4)P(7)O(24)and their tetrahedra-substituted phases M4Li(Li3P)P7O24(MLiP2O6, M = Cs, Rb) were designed and synthesized. Interestingly, two types of phases undergo a structural transformation, resulting from the radius and valence charge number of tetrahedral cations. Four crystals demonstrate potential deep-UV NLO properties such as short absorption edges (<190 nm) and phase-matching SHG response.
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