期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 62, 页码 8802-8805出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03934a
关键词
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资金
- EPSRC [EP/N025652/1, EP/P016618/1]
- EPSRC/Astex
- European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant [MSCA-IF-2017-795189]
- EPSRC [EP/P016618/1, EP/N025652/1] Funding Source: UKRI
A strategy for the beta-sp(3)functionalisation of cyclic amines is described. Regioselective conversion of protected amines to enecarbamates is achieved through electrochemical oxidation; these intermediates can be derivatised by functionalised alkyl halides under photoredox catalysis. The potential of the methods is highlighted by direct growth of a DCP2B-binding fragment.
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