4.7 Article

Dopamine polymer derived isolated single-atom site metals/N-doped porous carbon for benzene oxidation

期刊

CHEMICAL COMMUNICATIONS
卷 56, 期 63, 页码 8916-8919

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03620j

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资金

  1. National Key R&D Program of China [2017YFA0700101, 2016YFA0202801]
  2. National Natural Science Foundation of China [21925202, 21872076, 21590792, 21901007]
  3. Beijing Natural Science Foundation [JQ18007]
  4. Tsinghua University Initiative Scientific Research Program

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Isolated single-atom site metals/nitrogen-doped porous carbon (ISAS M/NPC, M = Fe, Co, Ni) catalysts are successfully prepared by a top-down polymerization-pyrolysis-etching-activation (PPEA) strategy, which uses dopamine as the precursor. Due to the isolated single atom Fe active sites and porous structure, the ISAS Fe/NPC catalyst displays a high benzene conversion up to 42.6% and nearly 100% phenol selectivity.

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