期刊
ANALYST
卷 145, 期 16, 页码 5500-5507出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0an00930j
关键词
-
资金
- National Natural Science Foundation of China [21565020]
Developing a rapid, low-cost, and multimode detection method for heavy metal ions remains a compelling goal for many applications, including food safety, environmental and biological analysis. This study investigated the influence of Hg(2+)on the peroxidase-like activity of gold nanoparticles (GNPs) decorated on carbon dots (CDs) from lysine (denoted as GNP@CDs). A new type of Hg2+-triggered peroxidase-like activity of GNP@CDs was discovered, which could catalyze the oxidation of the colorless 3,3 ',5,5 '-tetramethylbenzidine (TMB) into blue TMB. Based on the regulation of the catalytically triggered activity, a sensitive colorimetric method for the detection of Hg(2+)was developed, with a linear range of 7-150 nM, providing a limit of detection as low as 3.7 nM. The sensor is simple and rapid, and was successfully applied to the detection of Hg(2+)enrichment in chlorella, suggesting a promising application in biological analysis.
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