期刊
ORGANIC CHEMISTRY FRONTIERS
卷 7, 期 16, 页码 2255-2262出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00534g
关键词
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资金
- National Natural Science Foundation of China [21602097, 21601006]
- Heze University
The first enantioselective synthesis of atropisomeric 9-aryltetrahydroacridines was achieved through the condensation of 2-aminoaryl ketones with alicyclic ketones. The combination of chiral phosphoric acid and an achiral primary amine promoter proved to be a competent catalytic system. Moreover, the amenability of 4-substituted cyclohexanones enabled simultaneous generation of axial and point chirality.
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