期刊
ORGANIC CHEMISTRY FRONTIERS
卷 7, 期 16, 页码 2307-2312出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00555j
关键词
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资金
- Program for Innovative Research Team of the Ministry of Education, The Program of Liaoning Revitalization Talents Program [XLYC1808037]
- Syngenta Postgraduate Fellowship
A catalyst-free [4 + 2] cycloaddition-elimination of alpha-halogeno hydrazones with enaminones has been achieved under mild conditions. This protocol provides a novel and efficient method for the synthesis of pyridazine and tetrahydrocinnoline derivatives in good yields, with high functional group tolerance and remarkable regioselectivity. The process involves mechanistically distinct, cycloaddition and elimination reactions.
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