Response surface modelling of the biosorption of Zn(II) and Pb(II) ontoMicropogonias undulatusscales: Box-Behnken experimental approach

In this study, the scales ofMicropogonias undulatusfish were investigated as precursors for the development of low-cost biosorbent for the removal of Pb(II) and Zn(II) from aqueous media. The biosorbent was characterised using Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and X-ray diffractometry (XRD). Adsorption parameters (temperature, biosorbent dosage and contact time) were optimised using response surface methodology Box-Behnken experimental design. The optimal factors for Zn(II) removal by croaker fish scale were 145.5 min, 7.01 g/L biosorbent dosage, 30 degrees C and pH 5.4. The optimal factors for the removal of Pb(II) were 179.3 min, 6.61 g/L biosorbent dosage, 20 degrees C and pH 3.4. The numerical optimisation revealed that the optimal removal efficiency for Zn(II) and Pb(II) sorption is 96.45% and 98.76%, respectively. The biosorption of both heavy metals was best fit to Freundlich isotherm and pseudo-second-order kinetic models. Thermodynamics studies revealed that the biosorption process was exothermic and spontaneous.