期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 8, 期 31, 页码 15834-15844出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ta00689k
关键词
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资金
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0019215]
- U.S. Department of Energy, Office of Science [DE-AC02-06CH11357]
- Advanced Battery Materials Research (BMR) Program of the U.S. Department of Energy, Energy Efficiency and Renewable Energy, Office of Vehicle Technologies
- Air Force Office of Scienti.c Research [FA9550-16-1-0347, FA9550-18-1-0480.]
Transition metal chalcogenides with layered structures are promising materials for energy storage, catalysis, and electronics, among other areas. We have identified a new layered phase of iron sulfide containing interlayer solvated cations. We present an optimized synthesis for the Li+-containing material from an Fe(iii) xanthate complex. Structure and composition data indicate the material consists of poorly-ordered iron sulfide layers separated by solvated cations. The lamellar spacing in these materials can be tuned by changing the identity of the cation. Furthermore, the lamellar spacing can also be reversibly tuned by the degree of solvation of the material. The material is electrically conductive and can serve as a pseudocapacitor with comparable performance to commercial materials such as MnO2. Furthermore, these materials also show promise as lithium or sodium ion battery cathodes with good capacity and reversibility.
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